Accepted Thursday Sep 03, 2009
A recently developed high-field technique of atomic chains preparation has made it possible to attain the ultrahigh resolution of field-emission electron microscopy (FEEM), which can be used to direct imaging the intra-atomic electronic structure. By applying cryogenic FEEM, we are able to resolve the spatial configuration of atomic orbitals, which correspond to quantized states of the end atom in free-standing carbon atomic chains. Knowledge of the intra-atomic structure will make it possible to visualize generic aspects of quantum mechanics and also lead to new approaches for a wide range of nanotechnological applications.