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Phys. Rev. B 80, 155438 (2009) [7 pages]

Origin of the isotope effect on solid friction

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Yifei Mo1, Martin H. Müser2, and Izabela Szlufarska1
1Department of Materials Science and Engineering, University of Wisconsin–Madison, Madison, Wisconsin 53706, USA
2Universität des Saarlandes, Materialgerechtes Design und Werkstoffinformatik, Campus, Geb. C6.3, 66123 Saarbrücken, Germany

Received 19 June 2009; revised 20 September 2009; published 19 October 2009

Friction of hydrogen-passivated surfaces can be reduced by replacing terminating hydrogen atoms with heavier deuteriums. Using molecular-dynamics simulations, we show that this experimentally observed isotope effect can be explained quantitatively by small differences in surface coverage, which are due to isotope-dependent bond stabilities. We also demonstrate that a change in vibrational frequencies alone does not account for an isotope-dependent solid friction in our model system.

© 2009 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.80.155438
DOI:
10.1103/PhysRevB.80.155438
PACS:
81.40.Pq, 68.35.Np, 68.43.Nr, 68.43.Pq