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Phys. Rev. B 80, 014202 (2009) [6 pages]

Efficient local atomic packing in metallic glasses and its correlation with glass-forming ability

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D. Ma1,*, A. D. Stoica1, X-L. Wang1, Z. P. Lu2, M. Xu3, and M. Kramer3
1Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
2State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
3Materials and Engineering Physics, Ames Laboratory, Ames, Iowa 50011, USA

Received 29 January 2009; published 15 July 2009

We have probed local atomic structure of Zr-Cu metallic glasses using time-of-flight neutron and synchrotron x-ray diffraction techniques with high resolution. Our results provide evidence for a scheme of efficient local atomic packing where atomic clusters encompass multiple types of atoms in the first coordination shell. We also demonstrate experimental evidence of a strong correlation between the number of unlike atom bonds and the glass-forming ability. Our findings may provide insights into a broad range of scientific problems where efficient space filling by packing spheres is essential.

© 2009 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.80.014202
DOI:
10.1103/PhysRevB.80.014202
PACS:
61.05.J−, 75.50.Kj, 75.30.Gw, 68.37.Lp

*Corresponding author. dongma@ornl.gov