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Phys. Rev. B 79, 073411 (2009) [3 pages]

Simple connections in alkali adsorption

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J. W. Gadzuk*
Electron and Optical Physics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA

Received 23 October 2008; published 25 February 2009

Stimulated by recent two-photon photoemission spectroscopy and density-functional theory studies by Petek and co-workers, a retrospective look at some fundamentals in the theory of ionic alkali adsorption on metal surfaces is presented that provides a simple correlation between free-atom ionization potentials, ionic size, adsorption heights, and spectroscopically observed alkali valence-electron binding energies.

© 2009 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.79.073411
DOI:
10.1103/PhysRevB.79.073411
PACS:
73.20.Hb, 79.60.Dp

*gadzuk@nist.gov