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Phys. Rev. B 77, 081405(R) (2008) [4 pages]

Evidence for large hydrogen storage capacity in single-walled carbon nanotubes encapsulated by electroplating Pd onto a Pd substrate

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A. G. Lipson1,2,*, B. F. Lyakhov2, E. I. Saunin2, and A. Yu. Tsivadze2
1Department of Nuclear Plasma and Radiological Engineering, University of Illinois, Urbana, Illinois 61801, USA
2A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Received 10 October 2007; published 13 February 2008

We report a study of hydrogen storage in an alternative material, representing single-walled carbon nanotubes (SWCNTs) encapsulated by thin Pd layers onto a Pd substrate. A synergetic effect resulting in combination of the Pd and the SWCNTs properties with regards to hydrogen has been achieved. Adding SWCNTs increases the H2 capacity of the Pd-SWCNT composite by up to 25% relative to Pd metal alone under electrochemical loading. This results in a storage capacity of 8–12 wt %. with regard to the added SWCNTs.

© 2008 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.77.081405
DOI:
10.1103/PhysRevB.77.081405
PACS:
81.07.De, 61.46.−w, 61.82.Bg, 68.43.−h

*Corresponding author; lipson@uiuc.edu