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Phys. Rev. B 76, 054421 (2007) [8 pages]

Crystallographic phase transition within the magnetically ordered state of Ce2Fe17

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A. Kreyssig*, S. Chang, Y. Janssen, J. W. Kim, S. Nandi, J. Q. Yan, L. Tan, R. J. McQueeney, P. C. Canfield, and A. I. Goldman
Ames Laboratory USDOE and Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011, USA

Received 23 December 2006; published 10 August 2007

X-ray diffraction experiments were performed on polycrystalline and single-crystal specimens of Ce2Fe17 at temperatures between 10 and 300 K. Below Tt=118±2 K, additional weak superstructure reflections were observed in the antiferromagnetically ordered state. The superstructure can be described by a doubling of the chemical unit cell along the c direction in hexagonal notation with the same space group Rm as the room-temperature structure. The additional antiferromagnetic satellite reflections observed in earlier neutron diffraction experiments can be conclusively related to the appearance of this superstructure.

© 2007 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.76.054421
DOI:
10.1103/PhysRevB.76.054421
PACS:
61.10.Nz, 61.12.Ld, 61.50.Ks, 75.50.Bb

*Also at Institut für Festkörperphysik, Technische Universität Dresden, D-01062 Dresden, Germany; kreyssig@ameslab.gov