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Phys. Rev. B 72, 094113 (2005) [6 pages]

X-ray diffraction and Raman studies of beryllium: Static and elastic properties at high pressures

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W. J. Evans, M. J. Lipp, H. Cynn, and C. S. Yoo
H-Division, Physics and Advanced Technologies, Lawrence Livermore National Laboratory, Livermore, California 94551, USA

M. Somayazulu and D. Häusermann
HPCAT, Argonne National Laboratory, Carnegie Institution of Washington, Advanced Photon Source, Building 434E, 9700 South Cass Avenue, Argonne, Illinois 60439, USA

G. Shen and V. Prakapenka
GSECARS, CARS-The University of Chicago, Advanced Photon Source, Building 434A, 9700 S. Cass Ave., Argonne, Illinois 60439, USA

Received 29 May 2005; published 26 September 2005

We report combined x-ray and Raman studies of beryllium in helium and argon pressure media at pressures approaching 200 GPa. Our results are generally consistent with recent studies confirming the stability of the hexagonal close-packed phase to the highest pressures. However, the quasihydrostatic conditions of our studies lead to a stiffer equation of state (K0=109.88, K0=3.59) and a gradual approach toward a more ideal ca ratio of 1.60 at 180 GPa. Combining our Raman and equation of state data, we are able to evaluate the pressure dependence of the elastic shear modulus (C44=109.3, C44=1.959). We discuss the comparison of our results with measurements using ultrasonic and dynamic techniques.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.72.094113
DOI:
10.1103/PhysRevB.72.094113
PACS:
62.50.+p, 61.66.Bi, 64.30.+t, 63.20.−e