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Phys. Rev. B 72, 064114 (2005) [7 pages]

Relaxor ferroelectric characteristics and temperature-dependent domain structure in a (110)-cut (PbMg1∕3Nb2∕3O3)0.75(PbTiO3)0.25 single crystal

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X. Zhao, J. Y. Dai*, J. Wang, H. L. W. Chan, and C. L. Choy
Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, People’s Republic of China

X. M. Wan and H. S. Luo
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Science, 215 Chengbei Road, Jiading, Shanghai 201800, People’s Republic of China

Received 15 November 2004; published 23 August 2005

Relaxor ferroelectric characteristics of (110)-cut (PbMg1∕3Nb2∕3O3)0.75(PbTiO3)0.25 single crystal has been revealed by temperature-dependent hysteresis loops and dielectric permittivities measurements. Ferroelectric domain structure and evolution in the as-grown and the poled samples have also been studied by means of temperature-dependent piezoresponse force microscopy. The result from the as-grown single crystal reveals that the microdomain size distribution follows an exponential cutoff, and the crystal exhibits a transition from ferroelectric microdomain to paraelectric phase upon heating; while being cooled back to room temperature, new microdomains are rebuilt. By contrast, lamellar-shaped macrodomains have been observed in the poled sample and transitions from macro- to microdomain structures at 90 °C and from microdomain structure to paraelectric phase at 115 °C have been observed upon heating, respectively.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.72.064114
DOI:
10.1103/PhysRevB.72.064114
PACS:
77.84.−s, 68.37.Ps, 77.80.Dj, 77.65.−j

*Corresponding author. Electronic address: apdaijy@inet.polyu.edu.hk