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Phys. Rev. B 71, 073402 (2005) [4 pages]

Optical manifestations of the condensation of topological defects in continuous layer multishell carbon nanoparticles

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Peter V. Pikhitsa*, Young Jeong Kim, Myung Whun Kim, Sangsun Yang, Tae Won Noh, and Mansoo Choi
National CRI Center for Nano Particle Control, Institute of Advanced Machinery and Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742, Korea

Received 15 November 2004; published 2 February 2005

We report the observation and the explanation of the famous 220 nm spectral feature in UV absorption from continuous layer multishell carbon nanoparticles. Historically, attempts to find this feature in carbon allotropes led to the discovery of the C60 fullerene. We discerned the physical origin of this feature to be the well-defined pentagonal corner defects in polyhedral multilayer carbon nanoparticles. These new topological columnar defects should have large influence on the electronic properties of nanomaterials and are worthwhile further detail studying.

© 2005 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.71.073402
DOI:
10.1103/PhysRevB.71.073402
PACS:
61.46.+w, 61.48.+c

*On leave from Physics Institute, Odessa National University, Odessa, Ukraine.

ReCOE & School of Physics, Seoul National University, 151-747, Korea.

Author to whom correspondence should be addressed. Electronic address: mchoi@plaza.snu.ac.kr