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Phys. Rev. B 70, 205211 (2004) [5 pages]

Ni-vacancy defect in diamond detected by electron spin resonance

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K. Iakoubovskii*
Lab. Halfgeleiderfysica, Katholieke Universiteit Leuven, Celestijnenlaan 200 D, 3001 Leuven, Belgium and Department of Physics, King’s College London, Strand, London WC2R 2LS, United Kingdom

Received 28 April 2004; revised 19 July 2004; published 19 November 2004

Trigonal S=1 NOL1/NIRIM5 center has been characterized by electron spin resonance (ESR) in nickel and boron doped diamond grown by the high-pressure high-temperature technique. Hyperfine interaction structure has been detected and attributed to six equivalent carbon sites and one Ni site. Analysis of the ESR parameters strongly suggests assignment of the NOL1/NIRIM5 center to interstitial Ni2+ ion (3d8 configuration) situated in the center of a diamond divacancy.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.70.205211
DOI:
10.1103/PhysRevB.70.205211
PACS:
61.72.Ji, 76.30.Mi

*Electronic address: kostya.iak@fys.kuleuven.ac.be