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Phys. Rev. B 69, 201201(R) (2004) [4 pages]

Polyamorphic transition of germanium under pressure

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Emiliano Principi*
INFM, Università di Camerino, Dipartimento di Fisica, via Madonna delle Carceri, 62032 Camerino (MC), Italy

Andrea Di Cicco
INFM and INFN-LNF, Università di Camerino, Dipartimento di Fisica, via Madonna delle Carceri, 62032 Camerino (MC), Italy

Frédéric Decremps and Alain Polian
Physique des Milieux Condensés, CNRS, UMR 7602, Université Pierre et Marie Curie B 77, 4 place Jussieu, F-75252 Paris Cedex 05, France

Simone De Panfilis
ESRF, B.P. 220, 38043 Grenoble Cedex, France

Adriano Filipponi
INFM, Università dell’Aquila, Dipartimento di Fisica, via Vetoio 67010 Coppito, L’Aquila, Italy

See Also: Publisher's Note

Received 25 February 2004; published 18 May 2004; publisher error corrected 26 May 2004

Pressure-induced transformations in the atomic and electronic structure of amorphous germanium (a-Ge) have been investigated by using x-ray absorption spectroscopy (XAS) combined with energy-scanning x-ray diffraction. Our data show that an abrupt change in the local structure and in the electron states near the Fermi level occurs in evaporated a-Ge at a pressure of about 8 GPa. The transformation is clearly detectable by a change in the shape and energy shift in the near-edge structures and by an increase of the average first-neighbor distance measured by XAS. The occurrence of this polyamorphic transition is discussed in light of the recent advances in the study of multiple dense fluid phases.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.69.201201
DOI:
10.1103/PhysRevB.69.201201
PACS:
61.10.Ht, 61.43.Dq, 61.50.Ks, 64.70.-p

*Electronic address: emiliano.principi@unicam.it; URL: http://gnxas.unicam.it/∼principi/

See Also

Publisher's Note: Emiliano Principi, Andrea Di Cicco, Frédéric Decremps, Alain Polian, Simone De Panfilis, and Adriano Filipponi, Publisher's Note: Polyamorphic transition of germanium under pressure [Phys. Rev. B 69, 201201 (2004)], Phys. Rev. B 69, 249902 (2004).