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Phys. Rev. B 69, 014303 (2004) [7 pages]

Thermal and radiation-enhanced diffusion in the bulk metallic glass Ni23Zr62Al15

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S. Flege and H. Hahn
Institute of Materials Science, Darmstadt University of Technology, Petersenstr. 23, 64287 Darmstadt, Germany

R. S. Averback
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA

Received 21 May 2003; accepted 21 May 2003; published 29 January 2004

The temperature dependence of tracer diffusion in the three-component system NiZrAl was measured. For the composition Ni23Zr62Al15, it was possible to measure diffusion coefficients below and above the glass transition temperature. Similar to the binary metallic glass NiZr, the diffusion coefficient was strongly dependent on the atomic size of the tracer, varying by two orders of magnitude. The results are suggestive of a collective diffusion mechanism in bulk metallic glasses. Radiation-enhanced diffusion was also measured in this alloy and compared with measurements of radiation-induced viscous flow on similar alloys.

© 2004 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.69.014303
DOI:
10.1103/PhysRevB.69.014303
PACS:
66.30.Jt, 61.43.Dq