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Phys. Rev. B 67, 064406 (2003) [5 pages]

Unconventional magnetic transition and transport behavior in Na0.75CoO2

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T. Motohashi1,*, R. Ueda1, E. Naujalis1, T. Tojo1, I. Terasaki2, T. Atake1, M. Karppinen1, and H. Yamauchi1
1Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama 226-8503, Japan
2Department of Applied Physics, Waseda University, Tokyo 169-8555, Japan

Received 27 August 2002; revised 2 December 2002; published 6 February 2003

Here we report an unconventional magnetic and transport phenomenon in a layered cobalt oxide NaxCoO2. Only for x=0.75, a magnetic transition of the second order was clearly detected at Tm22K where an apparent specific-heat jump, an onset of extremely small spontaneous magnetization, and a kink in resistivity came in. Moreover large positive magnetoresistance effect was observed below Tm. These features of the transition strongly indicate the appearance of an unusual electronic state that may be attributed to the strongly correlated electrons in Na0.75CoO2.

© 2003 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.67.064406
DOI:
10.1103/PhysRevB.67.064406
PACS:
75.30.Kz, 71.30.+h, 72.15.Eb

*Electronic address: t-mot@msl.titech.ac.jp