Ordering kinetics in an fcc A₃B binary alloy model: Monte Carlo studies

Using an atom-vacancy exchange algorithm, we investigate the kinetics of the order-disorder transition in an fcc A₃B binary-alloy model following a temperature quench from the disordered phase. We observe two clearly distinct ordering scenarios depending on whether the final temperature T_f falls above or below the ordering spinodal T_sp, which is deduced from simulations at equilibrium. For shallow quenches (T_f>T_sp) we identify an incubation time τ_inc which characterizes the onset of ordering through the formation of overcritical ordered nuclei. The algorithm we use together with experimental information on tracer diffusion in Cu₃Au alloys allows us to estimate the physical time scale connected with τ_inc in that material. Deep quenches, T_f<T_sp, result in spinodal ordering. Coarsening processes at long times proceed substantially slower than predicted by the Lifshitz-Allen-Cahn t^1/2 law. Structure factors related to the geometry of the two types of domain walls that appear in our model are found to be consistent with Porod’s law in one and two dimensions.