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Phys. Rev. B 65, 132102 (2002) [3 pages]

Crystallization kinetics: A solution for geometrical impingement

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R. A. Clemente and A. M. Saleh*
Instituto de Fisica Gleb Wataghin, Universidade Estadual de Campinas, 13083-970 Campinas, Brazil

Received 27 September 2001; published 8 March 2002

Starting from the wrong derivation by Erukhimovitch and Baram of an equation alternative to the classical Kolmogoroff-Johnson-Mehl-Avrami one for the transformed fraction in an infinite specimen, undergoing an isothermal first-order phase transformation, it is shown that a different exact solution of the geometrical problem of impingement can be obtained. Such solution is equivalent to the empirical one already presented by Austin and Rickett more than sixty years ago and allows to better fit experimental results for isothermal transformations. This also suggests that perhaps different statistical derivations could allow to reach the same result.

© 2002 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.65.132102
DOI:
10.1103/PhysRevB.65.132102
PACS:
64.70.Dv, 81.10.Jt

*Also at Departamento de Matemática e Estatística, Universidade Estadual de Ponta Grossa, 84050-280 Ponta Grossa, Brazil.