corner
corner

Phys. Rev. B 64, 100201(R) (2001) [4 pages]

Evidence for long-range interactions between rare-earth impurity ions in nanocrystals embedded in amorphous matrices with the two-level systems of the matrix

Download: PDF (56 kB) Buy this article Export: BibTeX or EndNote (RIS)

R. S. Meltzer, W. M. Yen, and Hairong Zheng
Department of Physics and Astronomy, The University of Georgia, Athens, Georgia 30602

S. P. Feofilov
A. F. Ioffe Physical-Technical Institute, 194021 St. Petersburg, Russia

M. J. Dejneka
Corning Inc., Corning, New York 14831

B. M. Tissue and H. B. Yuan
Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061

Received 19 March 2001; published 22 August 2001

The low-temperature homogeneous broadening of the electronic transitions of Eu3+ and Pr3+ rare-earth impurity ions in Y2O3 and LaF3 nanocrystals embedded into amorphous materials (polymer and oxyfluoride glass ceramics) was studied with hole-burning and fluorescence line narrowing techniques. It is shown that the homogeneous linewidth is determined by the interaction of the impurity ions contained in the nanocrystals with the two-level systems (TLS’s) of the surrounding glass matrix. A comparison of the experiments with a calculation provides direct evidence for the long-range nature of the interaction with the TLS’s.

© 2001 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.64.100201
DOI:
10.1103/PhysRevB.64.100201
PACS:
78.67.-n, 78.67.Bf