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Phys. Rev. B 63, 012407 (2000) [4 pages]

Electron paramagnetic resonance spectra near the spin-glass transition in iron oxide nanoparticles

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Yu. A. Koksharov1, S. P. Gubin2, I. D. Kosobudsky3, G. Yu. Yurkov2, D. A. Pankratov4, L. A. Ponomarenko1, M. G. Mikheev1, M. Beltran5, Y. Khodorkovsky5, and A. M. Tishin1
1Faculty of Physics, M. V. Lomonosov Moscow State University, 119899, Moscow, Russia
2N. S. Kurnakov Institute of General and Inorganic Chemistry, 117091, Moscow, Russia
3Saratov State University, Chemical Department, 410026, Saratov, Russia
4Faculty of Chemistry, M. V. Lomonosov Moscow State University, 119899, Moscow, Russia
5Beltran, Inc., 1133 East 35th Street, Brooklyn, New York 11210

Received 17 April 2000; published 12 December 2000

Electron paramagnetic resonance (EPR) in iron-oxide nanoparticles (∼2.5 nm) embedded in a polyethylene matrix reveals the sharp line broadening and the resonance field shift on sample cooling below TF40K. At the same temperature a distinct anomaly in the field-cooled magnetization is detected. The temperature dependences of EPR parameters below TF are definitely different than those found for various nanoparticles in the superparamagnetic regime. In contrast to canonical bulk spin glasses, a linear fall-off of the EPR linewidth is observed. Such behavior can be explained in terms of the random-field model of exchange anisotropy.

© 2000 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.63.012407
DOI:
10.1103/PhysRevB.63.012407
PACS:
75.50.Lk, 75.50.Tt, 76.30.-v