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Phys. Rev. B 59, 8530–8540 (1999)

External pressure influence on ferroelectrics and antiferroelectrics of the KH2PO4 family: A unified model

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I. V. Stasyuk, R. R. Levitskii, and A. P. Moina
Institute for Condensed Matter Physics, 1 Svientsitskii Street, UA-290011, Lviv, Ukraine

Received 20 August 1998; published in the issue dated 1 April 1999

Within the four-particle cluster approximation for the proton ordering model, we study effects of external pressures which do not lower the crystals symmetry on deuterated ferroelectrics and antiferroelectrics of KH2PO4 family. The theory provides a satisfactory description of the available experimental data for transition temperature and static dielectric properties of the crystals and the experimentally observed universality of the transition temperature vs D-site distance dependence. Importance of the D-site distance in the phase transition and dielectric response of the hydrogen bonded crystals is shown.

© 1999 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.59.8530
DOI:
10.1103/PhysRevB.59.8530
PACS:
77.84.Fa