Phys. Rev. B 58, R14721–R14724 (1998)Magnetic-field-induced structural phase transition in Gd5(Si1.8Ge2.2)
We present direct evidence that the giant magnetocaloric effect recently discovered in the Gd5(Si1.8Ge2.2) alloy is associated with a field-induced first-order structural transition from a P1121/a monoclinic (paramagnetic) to a Pnma orthorhombic (ferromagnetic) structure. A large volume contraction of ΔV/V≅0.4% takes place spontaneously at the transition temperature, TC≅240K. The reported structural transition can be induced reversibly by application of an external magnetic field, producing strong magnetoelastic effects. © 1998 The American Physical Society URL:
http://link.aps.org/doi/10.1103/PhysRevB.58.R14721
DOI:
10.1103/PhysRevB.58.R14721
PACS:
75.30.Kz, 75.50.Cc, 75.80.+q
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