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Phys. Rev. B 50, 4260–4263 (1994)

Superconductivity up to 164 K in HgBa2Cam-1CumO2m+2+δ (m=1, 2, and 3) under quasihydrostatic pressures

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L. Gao, Y. Y. Xue, F. Chen, Q. Xiong, R. L. Meng, D. Ramirez, and C. W. Chu
Department of Physics and Texas Center for Superconductivity, University of Houston, Houston, Texas 77204-5932

J. H. Eggert and H. K. Mao
Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Road NW, Washington, D.C. 20015-1305

The superconducting transition temperatures (Tc’s) of optimally doped HgBa2Cam-1CumO2m+2+δ (Hg 1:2:m-1:m) with m=1, 2, and 3 and Hg1-xPbxBa2Ca2Cu3O8+δ [Hg(xPb) 1:2:2:3] have been investigated resistively under quasihydrostatic pressures up to 45 GPa. There seems to be a universal upward shift of Tc under pressure, regardless of m, for all Hg 1:2:m-1:m, implying a common origin for all compounds. Record high Tc’s of 164, 154, and 118 K were reached for the optimally doped Hg 1:2:m-1:m with m=3, 2, and 1, respectively. However, the Tc enhancement is suppressed by Pb substitution, suggesting the possibility that Hg plays an important role in these compounds.

© 1994 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.50.4260
DOI:
10.1103/PhysRevB.50.4260
PACS:
74.72.Jt, 74.62.Fj