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Phys. Rev. B 50, 8170–8181 (1994)

Dynamical local-field factors and effective interactions in the three-dimensional electron liquid

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C. F. Richardson and N. W. Ashcroft
Laboratory of Atomic and Solid State Physics and Materials Science Center, Cornell University, Ithaca, New York 14853-2501

Received 22 February 1994; published in the issue dated 15 September 1994

We present a study of the local-field factors for the homogeneous, isotropic, three-dimensional interacting electron liquid as a function of momentum, imaginary frequency (iw), and density (rs). A variational approach is used to solve integral equations for the density-density and spin-spin response functions, and it provides approximations to the local-field factors which are exact in the high-density limit. We derive sum rules which show that for large iw, the local-field factors possess maxima (in both q and iw) whose magnitudes are related to the pair-distribution function evaluated at zero separation. We introduce a parametrization scheme which incorporates these sum rules with the known compressibility, susceptibility, and third-moment sum rules. The local-field factors are then used to calculate the effective electron-electron interaction using the Vignale-Singwi formalism [Phys. Rev. B 32, 2156 (1985)]. It is found to be significantly larger than that predicted by Hubbard-type local-field factors for small to intermediate values of the wave vector and imaginary frequency.

© 1994 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.50.8170
DOI:
10.1103/PhysRevB.50.8170
PACS:
71.45.Gm, 05.30.Fk, 71.10.+x