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Phys. Rev. B 47, 9760–9777 (1993)

Morphological instability in epitaxially strained dislocation-free solid films: Nonlinear evolution

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B. J. Spencer and S. H. Davis
Department of Engineering Sciences and Applied Mathematics, Northwestern University, Evanston, Illinois 60208

P. W. Voorhees
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208

Received 19 August 1992; published in the issue dated 15 April 1993

We consider a continuum model for the evolution of an epitaxially strained dislocation-free solid film on a rigid substrate in the absence of vapor deposition. In the context of this model a planar film is unstable for film thicknesses greater than a critical thickness and the instability is characterized by long waves at the critical thickness. By exploiting the long-wave nature of the instability we are able to derive a nonlinear evolution equation for the film surface. We examine the nonlinear evolution equation for two-dimensional steady states and find subcritical spatially periodic finite-amplitude rounded-cusp steady solutions as well as near-critical spatially periodic small-amplitude steady solutions. We analyze these solutions for stability and find them all to be unstable. Our analysis suggests that there are no stable two-dimensional steady states that can be described by long-wave theory. Thus, the evolution of the film may be to a steady state outside the realm of long-wave theory or to a transient state characterized by coarsening.

© 1993 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.47.9760
DOI:
10.1103/PhysRevB.47.9760
PACS:
47.20.Hw, 47.20.Ky, 61.50.Cj, 68.55.-a