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Phys. Rev. B 32, 3003–3005 (1985)

Phase diagram of LixMo6Se8 for 0<x<1 from in situ x-ray studies

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J. R. Dahn and W. R. McKinnon
Solid State Chemistry, Division of Chemistry, National Research Council of Canada, Ottawa, Canada K1A OR9

Received 8 April 1985; published in the issue dated 1 September 1985

The intercalated Li in LixMo6Se8 separates into regions of high and low concentration below a critical temperature Tc=267 K. The phase diagram agrees with a mean-field solution to a lattice-gas model of intercalation in LixMo6Se8. The implications of this agreement are considered.

© 1985 The American Physical Society

URL:
http://link.aps.org/doi/10.1103/PhysRevB.32.3003
DOI:
10.1103/PhysRevB.32.3003
PACS:
84.60.Fq, 64.70.Kb, 64.75.+g